127411-83-0

Basic information

• Product Name: Trimethyl-{1-[3-phenyl-prop-(E)-ylidene]-pentyl}-silane
• CAS NO: 127411-83-0
• Molecular Weight: 260.495
• Mol File: 127411-83-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trimethyl-{1-[3-phenyl-prop-(E)-ylidene]-pentyl}-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl-{1-[3-phenyl-prop-(E)-ylidene]-pentyl}-silane(127411-83-0)
• EPA Substance Registry System: Trimethyl-{1-[3-phenyl-prop-(E)-ylidene]-pentyl}-silane(127411-83-0)

Safety Data

• Hazardous Substances Data: 127411-83-0(Hazardous Substances Data)

Upstream product

• 100347-31-7 C₁₆H₃₆Ce^(1-)*Li⁽¹⁺⁾ 
• 127411-76-1 (Z)-4-phenyl-1-trimethylsilyl-1,2-epoxybutane 
• 127411-81-8 C₄H₉Cl₂La 
• 497107-80-9 (E)-4-phenyl-1-trimethylsilyl-1,2-epoxybutane 
• 127411-79-4 C₄H₉Cl₂Sm 
• 94616-73-6 n-butylcerium dichloride 
• 127411-78-3 C₄H₉Cl₂La 

Relevant articles and documents

Stereoselective Syntheses of Carbon Homologated Vinylsilanes and Desilylated Olefins from α,β-Epoxy Silanes Using Organolithium and Organolanthanoid Reagents

Synchronous insertion of alkyl group and deoxygenation reaction were achieved from α,β-epoxy silanes by the treatment with organolithium or organolanthanoid reagents in a regio- and stereoselective manner, i.e., the reaction of (Z)-α,β-epoxy silanes gave the corresponding alkylated (Z)-vinylsilanes, and (E)-α,β-epoxy silanes were transformed into desilylated alkylated (E)-olefins.