127422-15-5Relevant articles and documents
(Diisopinocampheyl)borane-mediated reductive aldol reactions of acrylate esters: Enantioselective synthesis of anti-aldols
Allais, Christophe,Nuhant, Philippe,Roush, William R.
, p. 3922 - 3925 (2013/09/02)
The (diisopinocampheyl)borane promoted reductive aldol reaction of acrylate esters 4 is described. Isomerization of the kinetically formed Z(O)-enolborinate 5Z to the thermodynamic E(O)-enolborinate 5E via 1,3-boratropic shifts, followed by treatment with
Lewis base activation of Lewis acids: Catalytic, enantioselective addition of silyl ketene acetals to aldehydes
Denmark, Scott E.,Beutner, Gregory L.,Wynn, Thomas,Eastgate, Martin D.
, p. 3774 - 3789 (2007/10/03)
The concept of Lewis base activation of Lewis acids has been reduced to practice for catalysis of the aldol reaction of silyl ketene acetals and silyl dienol ethers with aldehydes. The weakly acidic species, silicon tetrachloride (SiCl4), can b
Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols
Corey,Kim, Sung Soo
, p. 4976 - 4977 (2007/10/02)
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