127446-20-2Relevant academic research and scientific papers
Chemistry of Amino Oximes, XIX. - Reaction of β-Benzylamino Oximes with Sulfuryl Chloride
Gnichtel, Horst,Koehler, Christoph
, p. 775 - 779 (2007/10/02)
3,4-Dihydro-2H-1,2,6-thiadiazine 1,1,6-trioxides 2 were prepared from anti-β-benzylamino oximes 1 and sulfuryl chloride.Tetrahydro-2H-1,2,6-thiadiazin 1,1-dioxides 3 were formed by reduction with NaBH4 and β-hydroxylimino sulfamic acid derivatives by hydrolysis, alkoholysis, and aminolysis with secondary amines.With primary amines, 2 afforded pyrazolines 7; syn-β-benzylamino oximes 9 and sulfuryl chloride yielded pyrazolines 10.
