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LOW TEMPERATURE KETENE PREPARATIONS USING NITROSYLTETRACARBONYLCHROMIUM (-II) ANION
Masters, A. P.,Sorensen, T. S.
, p. 5869 - 5872 (1989)
Methylene and cyclopropyl ketenes can be generated at -100 deg C by the dehalogenation of α-bromoacylhalides using nitrosyltetracarbonylchromium (-II) anion.This facilitates the trapping of these ketenes with more stable ketenes to give mixed ketene dimers.
