127530-30-7

Basic information

• Product Name: 2-fluoro-<α,α-²H2>benzyl alcohol
• Synonyms: 2-fluoro-<α,α-²H2>benzyl alcohol
• CAS NO: 127530-30-7
• Molecular Weight: 128.115
• Mol File: 127530-30-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-fluoro-<α,α-²H2>benzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-fluoro-<α,α-²H2>benzyl alcohol(127530-30-7)
• EPA Substance Registry System: 2-fluoro-<α,α-²H2>benzyl alcohol(127530-30-7)

Safety Data

• Hazardous Substances Data: 127530-30-7(Hazardous Substances Data)

Upstream product

• 443-26-5 2-fluoro-benzoic acid ethyl ester 
• 394-35-4 methyl 2-fluorobenzoate 

Downstream Products

• 107135-16-0 α-deuterio-o-fluorobenzaldehyde tosylhydrazone 
• 185435-44-3 3-(2-{[(tert-butyldimethylsilyl)oxy][²H₂]methyl}phenyl)-10-(4-tert-butylphenyl)[5-²H]pyrimido[4,5-b]quinoline-2,4(3H,10H)-dione 
• 1026501-87-0 C₂₈H₂₄⁽²⁾H₃N₃O₃ 
• 185435-45-4 10-(4-tert-butylphenyl)-3-[2-(trifluoromethyl)phenyl][5-²H]pyrimido[4,5-b]quinoline-2,4(3H,10H)-dione 
• 185435-43-2 10-(4-tert-butylphenyl)-3-(2-methylphenyl)[5-²H]pyrimido[4,5-b]quinoline-2,4(3H,10H)-dione 
• 107135-17-1 2-fluoro-<α-²H>benzaldehyde 

Relevant articles and documents

Supersonic Jet Studies of Benzyl Alcohols: Minimum Energy Conformations and Torsional Motion

Supersonic jet mass resolved excitation spectroscopy is employed to determine the minimum energy conformations of benzyl alcohol and a series of nine methyl-, ethyl-, fluoro-, and aminobenzyl alcohols. The interpretation of the mass resolved excitation sp

An α, α - dideuterium substituted benzyl alcohol compound. Deuterated drug and method for reducing deuteration of benzoate compound

The invention relates to a method. Α, α-deuterated benzyl alcohol compound and preparation thereofΑ, αThe method for reducing and deuteration - dideuterium-substituted benzyl alcohol compounds is characterized in that the benzoate compound represented by

1,2,4,6-CYCLOHEPTATETRAENE: THE KEY INTERMEDIATE IN ARYLCARBENE INTERCONVERSIONS AND RELATED C7H6 REARRANGEMENTS

Thermolysis or photolysis of phenyldiazomethane (2) produces phenylmethylene (3), which ring-expands to give 1,2,4,6-cycloheptatetraene (6).Spectroscopic and chemical evidence rule out bicyclo(4.1.0)hepta-2,4,6-triene (4), cycloheptatrienylidene (5), and bicyclo(3.2.0)hepta-1,3,6-triene (11) intermediates.The strained allene in cycloheptatetraene (6) exhibits infrared absorption at 1824 and 1816 cm-1.Deuterium substitution produces the expected 10-cm-1 shift in the allene absorption.Fluorine or chlorine substitution substantially enhances the allene absorption intensity.Deuterium labeling studies reveal that the intramolecular chemistry of cycloheptatetraene (6) involves reversible thermal or photochemical equilibriation with phenylmethylene (3).The intermolecular chemistry of 6 involves dimerization.At temperatures as low as 10 K, 6 forms a labile (2+2) dimer,7, which undergoes thermally allowed, electrocyclic ring opening to give heptafulvalene (8) upon warming to room temperature.The rearrangements of 7-acetoxynorbornadiene (9), 2-diazobicyclo(3.2.0)hepta-3,6-diene (31), and 8-diazobicyclo(2.2.2)octa-2,5-dien-7-one (33) all involve cycloheptatetraene (6) intermediates.