1275615-81-0Relevant academic research and scientific papers
Synthesis of highly functionalized cyclohexenone rings: Rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition
Shu, Dongxu,Li, Xiaoxun,Zhang, Min,Robichaux, Patrick J.,Tang, Weiping
, p. 1346 - 1349 (2011)
Lead Rh-ole: Highly substituted cyclohexenones were prepared from cyclopropyl-substituted propargyl esters by using a [{Rh(CO)2Cl} 2] catalyst. This metal catalyst promoted the 1,3-acyloxy migration of propargyl esters and a subsequent [5+1] cycloaddition of the resulting allenylcyclopropanes in the presence of CO with high regioselectivity.
