127563-75-1Relevant academic research and scientific papers
STUDY OF THE REACTION OF SODIUM AMIDE IN LIQUID AMMONIA WITH HEXAHYDRO-(1H)-2-BENZAZONINIUM SALTS: ACCESS TO 2-AZA-(7)-METACYCLOPHANES
Barbry, Didier,Spanneut, Damien,Hasiak, Bruno,Couturier, Daniel
, p. 47 - 52 (2007/10/02)
The rearrangement of hexahydro-(1H)-2-benzazoninium ylides in liquid ammonia yields a mixture of amines: metacyclophanes arise from Sommelet-Hauser transposition, alkenes from an Hofmann elimination, enamines from a process which is discussed here, and tw
EVOLUTION THERMIQUE DE DERIVES DES HEXAHYDROBENZAZOCINES-2 ET DES HEXAHYDRO-1H-BENZAZONINES-2 N-QUATERNARISES (AMMONIUMS, N-OXYDES)
Elmasmodi, Abdellatif,Barbry, Didier,Hasiak, Bruno,Couturier, Daniel
, p. 2767 - 2774 (2007/10/02)
La thermolyse des hydroxydes d'ammonium derives des hexahydrobenzazocines-2 et de la methyl-2-hexahydro-1H benzazonine-2 conduit a un melange de composes ethyleniques .Les N-oxydes de N-methyl hexahydrobenzazocines-2 se decomposent thermiquement en derives de l'oxa-2 hexahydro-1H-benzazonines-3 souilles de la benzazocine de depart.
