127579-32-2Relevant academic research and scientific papers
DIASTEREOSELECTIVITY IN THE TiCl4-MEDIATED ALDOL REACTION OF CYCLIC DIENYLSILYL ETHERS
Barner, Bruce A.,Liu, Yalei,Rahman, Md. Abdur
, p. 6101 - 6112 (2007/10/02)
Cyclic dienylsilyl ethers derived from α,β-unsaturated ketones undergo TiCl4-catalyzed crossed aldol reactions with aldehydes, giving β'-hydroxy enone systems with good diastereoselectivity in most cases.The direction of stereocontrol (syn versus anti) in
