127583-05-5Relevant articles and documents
Stereospecific 1,2-Rearrangement of Cyclopropyl Group. Synthesis of Chiral α-Cyclopropyl Ketones and α-Cyclopropyl Aldols
Shimazaki, Masato,Hara, Hisaaki,Suzuki, Keisuke
, p. 5443 - 5446 (1989)
Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined α-cyclopropyl ketones and α-cyclopropyl aldols.Acceleration of the reaction by the introduction of trimethylsilyl(TMS) group to the α-position of cy