127594-97-2Relevant academic research and scientific papers
Efficient Conversions of Thioethers to α-Fluoro Thioethers with DAST or DAST/Antimony(III) Chloride
Robins, Morris J.,Wnuk, Stanislaw F.
, p. 3800 - 3801 (2007/10/02)
Dialkyl or alkyl aryl thioethers, including nucleoside thioethers, undergo virtually quantitative conversion to α-fluoro thioethers with (diethylamino)sulfur trifluoride (DAST) in dichloromethane at ambient temperature.Antimony(III) chloride catalyzes the process.
