127598-08-7

Upstream product

• 127597-99-3 (3S)-2,5-Dimethyl-3-(N-tosylamino)-1-hexene 
• 150062-26-3 (3S)-anti-2,5-Dimethyl-3-hexan-1-ol 
• 103127-72-6 (3S)-5-Methyl-3-(N-tosylamino)-2-hexanone 
• 150062-22-9 (3S)-2,5-Dimethyl-3--1-hexene 
• 98-59-9 p-toluenesulfonyl chloride 
• 61-90-5 L-leucine 
• 1220-80-0 (S)-4-methyl-2-(toluene-4-sulfonamido)pentanoic acid 

Relevant academic research and scientific papers

Manipulation of Substrate-Controlled Diastereoselectivities in Hydroborations in Acyclic Allylamine Derivatives

Racemic, and optically active, 2-methyl-3-(N-tosylamino)alkenes I were prepared and subjected to both catalyzed and uncatalyzed hydroborations.Data obtained for the catalyzed hydroborations of these allylamine derivatives are consistent with the theory of

SUBSTRATE-CONTROLLED DIASTEREOSELECTIVITY IN CATALYZED AND UNCATALYZED HYDROBORATIONS OF ALLYLIC AMINE DERIVATIVES

Hydroboration of the protected, homochiral allylic amines (6)-(10) with 9-BBN, and with catecholborane/rhodium catalyst, give different stereoselectivities; the catalyzed reactions provide access to syn-3-amino-2-methyl alcohols (11)-(15).