1276069-52-3Relevant academic research and scientific papers
Efficient one-to-one coupling of easily available 1,3-dienes with carbon dioxide
Takaya, Jun,Sasano, Kota,Iwasawa, Nobuharu
supporting information; experimental part, p. 1698 - 1701 (2011/05/04)
An efficient one-to-one coupling reaction of atmospheric pressure carbon dioxide with 1,3-dienes is realized for the first time through PSiP-pincer type palladium-catalyzed hydrocarboxylation. The reaction is applicable to various 1,3-dienes including easily available chemical feedstock such as 1,3-butadiene and isoprene. This protocol affords a highly useful method for the synthesis of β,γ-unsaturated carboxylic acid derivatives from CO2.
