127654-87-9Relevant academic research and scientific papers
LITHIATION OF ORTHO-TOLYL TETRAMETHYLPHOSPHORODIAMIDATES: A FACILE SYNTHESIS OF 2- ARYLBENZOFURANS INCLUDING NEOLIGNAN, CARINATIN
Date, Matsuhiro,Kawanishi, Kenji,Hori, Takako,Watanabe, Mitsuaki,Furukawa, Sunao
, p. 2884 - 2886 (2007/10/02)
ortho-Tolyl tetramethylphosphorodiamidates were lithiated with sec-BuLi at -105 deg C to give corresponding benzylic lithio species which underwent reaction with electrophiles.When benzoates were used as electrophiles, deoxybenzoin derivatives were obtain
