127666-20-0

Basic information

• Product Name: 3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-5-O-(diphenylphosphinyl)-α-D-glucofuranose
• Synonyms: 3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-5-O-(diphenylphosphinyl)-α-D-glucofuranose
• CAS NO: 127666-20-0
• Molecular Weight: 620.421
• Mol File: 127666-20-0.mol

Chemical Properties

• CAS DataBase Reference: 3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-5-O-(diphenylphosphinyl)-α-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-5-O-(diphenylphosphinyl)-α-D-glucofuranose(127666-20-0)
• EPA Substance Registry System: 3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-5-O-(diphenylphosphinyl)-α-D-glucofuranose(127666-20-0)

Safety Data

• Hazardous Substances Data: 127666-20-0(Hazardous Substances Data)

Upstream product

• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 19877-13-5 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose 

Relevant articles and documents

A Novel Route to Olefins from Vicinal Diols

A novel reagent system consisting of chlorodiphenylphosphine, imidazole, and iodine in an inert solvent converts vicinal diols to olefins.Reagents are, after completed reaction, removed by extractive procedures, which facilitates large-scale preparations.Vicinal diols consisting of either a primary and a secondary hydroxyl or two secondary hydroxyls are in this way converted to olefins in high yields.