127679-03-2

Basic information

• Product Name: (E)-1-chloro-4-methyl-hept-3,6-diene
• CAS NO: 127679-03-2
• Molecular Weight: 144.644
• Mol File: 127679-03-2.mol

Chemical Properties

• CAS DataBase Reference: (E)-1-chloro-4-methyl-hept-3,6-diene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-chloro-4-methyl-hept-3,6-diene(127679-03-2)
• EPA Substance Registry System: (E)-1-chloro-4-methyl-hept-3,6-diene(127679-03-2)

Safety Data

• Hazardous Substances Data: 127679-03-2(Hazardous Substances Data)

Upstream product

• 765-43-5 Cyclopropyl methyl ketone 
• 762-72-1 allyl-trimethyl-silane 

Relevant articles and documents

Etude de la reactivite de l'allyltrimethylsilane avec les cetones α-cyclopropaniques en presence de tetrachlorure de titane

The reaction of diversely substituted α-cyclopropylketones with allyltrimethylsilane in the presence of titanium tetrachloride has been studied.The products formation is explained by the intervention of a cyclopropylcarbinyl transient cation formed after a first 1,2-addition on the carbonyl.With regard to the structure of the starting compounds, this intermediate reacts with a second molecule of allylsilane, either by a bimolecular addition on the carbocycle, or by the direct attack on the carbon bearing the formal positive charge yielding diallyl and functionalisedcyclohexane derivatives.A general mechanism is proposed.Keywords: Silicon; Titanium; Allyltrimethylsilane; Lewis acids; Reaction mechanism

Reactivite de l'allyltrimethylsilane avec les acetylcyclopropanes en presence d'acide de Lewis

In the presence of Lewis acid, allyltrimethylsilane undergoes 1,2-addition to the carbonyl system of acetylcyclopropanes.A second direct attack of the nucleophilic reagent on the transient cyclopropylcarbynyl cation formed yields diallylic and functionalised cyclohexane derivatives.