127679-11-2Relevant academic research and scientific papers
Contribution a l'evaluation de l'importance des facteurs electroniques et steriques gouvernant la reaction des boranes avec les azides
Carboni, Bertrand,Vaultier, Michel,Courgeon, Thierry,Carrie, Robert
, p. 844 - 849 (2007/10/02)
Organoboranes react with azides to give, after hydrolysis, secondary amines.Scope and limitations of this method have been stated.When dibromoboranes were used, a competitive migration of the alkyl group and bromine leading to the simultaneous formation of a tetraazaboroline and the expected secondary amine was observed.A mechanism accounting for these results is proposed.
