127700-38-3Relevant academic research and scientific papers
A Convenient Synthesys of 1,1-Difluoroallenes from Trifluoromethylketones via the Shapiro Reaction Pathway
Shi, Guoqiang,Xu, Yuanyao
, p. 161 - 166 (1989)
A number of 1,1-difluoroallenes have been conveniently synthesized by means of the Shapiro reaction.The requisite trifluoromethylketone 2,4,6-triisopropylbenzenesulfonylhydrazones were prepared by a simple condensation method.The geometric features relating to their reactivity towards the Shapiro reaction have been discussed.
A Facile Synthesis of α-Trifluorodiazo Compounds
Shi, Guoqiang,Xu, Yuanyao
, p. 173 - 178 (2007/10/02)
A variety of α-trifluorodiazo compounds which can be used as building blocks for the construction of organic molecules bearing a trifluoromethyl group have been prepared in high yields simply by refluxing trifluoromethylketone 2,4,6-triisopropylbenzenesul
