1277149-95-7Relevant academic research and scientific papers
A selective transformation of enals into chiral γ-amino alcohols
Calow, Adam D. J.,Batsanov, Andrei S.,Pujol, Alba,Sole, Cristina,Fernandez, Elena,Whiting, Andrew
, p. 4810 - 4813 (2013)
A one-pot synthesis of chiral amino alcohols from α,β- unsaturated aldehydes is reported which circumvents competitive 1,2- versus 1,4-boryl addition, by means of using a sterically hindered amine-derived imine. In addition to the complete chemoselectivit
Enantioselective rhodium-catalyzed [4 + 2] cycloaddition of α,β-unsaturated imines and isocyanates
Oberg, Kevin M.,Rovis, Tomislav
supporting information; experimental part, p. 4785 - 4787 (2011/05/16)
A [4 + 2] cycloaddition of α,β-unsaturated imines and isocyanates catalyzed by a phosphoramidite-rhodium complex provides pyrimidinones in good yields and high enantioselectivities.
