1277163-39-9Relevant articles and documents
Beyond the corey reaction II: Dimethylenation of sterically congested ketones
Barabash, Anastasiya V.,Butova, Ekaterina D.,Kanyuk, Igor M.,Schreiner, Peter R.,Fokin, Andrey A.
, p. 10669 - 10673 (2014)
Bulky methyl ketones show significantly decreased reactivities toward the Corey-Chaykovsky methylenation reagent dimethylsulfoxonium methylide (DMSM). The excess of base and temperature increase opens an alternative reaction channel that instead leads to
