127757-23-7Relevant academic research and scientific papers
Synthesis of Prenylated Quinones by the Oxydative Degradation Approach. Birch vs Vinylogous Birch Hydrogenolysis (BIHY vs VIBIHY) in Controlling Δ2 Stereochemistry of the Prenyl Chain
Ballester, Pablo,Capo, Magdalena,Garcias, Xavier,Saa, Jose M.
, p. 328 - 334 (2007/10/02)
Two novel approaches toward prenylated quinones are described.The first (route A) involves the following three basic operations: (a) construction of a 4-hydroxybenzylamine carrying a tertiary allyl alcohol (cinnamyl alcohol) side chain of appropriate leng
Prenylation of aromatics. Lithium-ammonia reduction of o-silylated tertiary cinnamyl alcohols
Ballester, Pablo,Capo, Magdalena,Saa, Jose M.
, p. 1339 - 1342 (2007/10/02)
Silyl protected phenolic or non-phenolic tertiary cinnamyl alcohols undergo metalammonia induced hydrogenolysis with concomitant double bond isomerization, thus providing a unique entrance to prenyl substituted aromatics. Chiral alcohols yielded E:Z mixtu
