127776-35-6Relevant academic research and scientific papers
Unusually Stable Monothiolate and S/N, S/O Mixed Ligand Complexes of Iron(III) Tetramesitylporphyrin
Brewer, C.
, p. 344 - 346 (2007/10/02)
The reaction of tetramesitylporphinatoiron(III) hydroxide with ethyl 3-mercaptopropionate in toluene generates the air and temperature stable five co-ordinate iron(III) monothiolate complex, which adds imidazole or other Lewis base to give a six co-ordinate adduct, the unusual stability of which allows characterisation by UV-VIS spectrophotometry at room temperature.
