127783-06-6

Upstream product

• 862731-40-6 phenyl 3,4-di-O-acetyl-2-deoxy-1-thio-L-rhamnopyranoside 
• 100-51-6 benzyl alcohol 
• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 132064-85-8 benzyl 3,4-di-O-acetyl-2,6-dideoxy-2-iodo-α-L-mannopyranoside 

Downstream Products

• 132064-88-1 benzyl 3-O-benzoyl-2,6-dideoxy-4-O-tosyl-α-L-arabino-hexopyranoside 
• 132064-89-2 benzyl 4-azido-3-O-benzoyl-2,4,6-trideoxy-α-L-lyxo-hexopyranoside 
• 113756-98-2 benzyl 4-O-benzoyl-2,6-dideoxy-α-L-arabino-hexopyranoside 
• 132064-86-9 benzyl 3-O-benzoyl-2,6-dideoxy-α-L-arabino-hexopyranoside 
• 132064-90-5 benzyl 4-azido-2,4,6-trideoxy-α-L-lyxo-hexopyranoside 
• 132064-91-6 benzyl 4-amino-2,4,6-trideoxy-α-L-lyxo-hexopyranoside 
• 127783-07-7 benzyl 2,6-dideoxy-α-L-arabino-hexopyranoside 

Relevant academic research and scientific papers

Tagged hypervalent iodine reagents: A new purification concept based on ion exchange through SN2 substitution

(Chemical Equation Presented) The preparation of phenylsulfonate-tagged iodine(III) reagents as well as their use in a novel purification strategy for iodine(III)-promoted reactions is described. The concept is based on ion exchange and is initiated by an azide-promoted SN2-reaction at the alkyl sulfonate followed by trapping of the resulting aryl sulfonate anion with an ion-exchange resin. The concept is successfully proven for Ru-catalyzed oxidations of alcohols, the activation and glycosidatlon of thioglycosides, and the Suarez reaction of pyranoses.

Synthesis of 4-O-methyl-β-rhodomycins using derivatives of 4-amino-4-deoxy- and 3,4-diamino-3,4-dideoxy sugars

Synthesis of 7-O-(4-amino-2,4,6-trideoxy- and 7-O-(3,4-diamino-2,3,4,6-tetradeoxy-α-L-lyxo-hexopyranosyl)-4-O-methyl-β-rhodomycinones (31 and 33) are described.The glycosyl donors 2,4,6-trideoxy-1,3-di-O-p-nitrobenzoyl-4-trifluoroacetamido-β-L-lyxo-hexopy