127818-07-9

Upstream product

• 127783-19-1 (1R,2S,4R,7R,9S,12R)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.0^2,7>-tetradec-10-ene 
• 127910-93-4 Methyl 4,6-O-Benzylidene-2,3-dideoxy-3,2-C-<(3'R)-3'-hydroxybutan-1'-yl-4'-ylidene>-3-C-methyl-α-D-arabino-hexopyranoside 
• 127783-20-4 (1R,2S,4R,7R,9S,10R,11S,15R)-9-methoxy-1,13,13-trimethyl-4-phenyl-3,5,8,14-tetraoxa-13-silatetracyclo<8.7.0.0^2,70^11,15>heptadecane 

Downstream Products

• 146861-60-1 Benzoic acid (R)-1-[(1R,2R,3R,4R)-4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-formyl-1-methyl-cyclohexyl]-allyl ester 
• 146861-62-3 Benzoic acid (S)-1-[(1R,2R,3R,4R)-4-(tert-butyl-diphenyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-2-triethylsilanyloxymethyl-cyclohexyl]-2-oxo-ethyl ester 

Relevant academic research and scientific papers

Stereoselective Reductive Hydroxymethylation of an Annulated Sugar Derivative via Radical Cyclisation

Addition of a silylmethylene and hydride radical to the carbon-carbon double of two allylic silyl ethers derived from annulated carbohydrates has been shown to occur in an anti fashion.

The Stereochemistry of the Stork Silyl Methylene Radical Cyclisation in an Annulated Sugar Derivative

Annulated sugar derivatives with α- and β-allylic alcohol groups have been subjected to the Stork silyl methylene radical cyclisation reaction, in both cases, trans-addition of the radical occurred to produce a new fused ring system.