1278520-82-3Relevant academic research and scientific papers
Formation of CuI(CH3CN)4ClO4 in the reactions of copper(II) perchlorate with acetonitrile in the presence of sulfur-containing organic compounds
Beloglazkina,Shimorsky,Mazhuga,Shilova,Tafeenko,Zyk
experimental part, p. 1504 - 1508 (2009/12/04)
Cu(ClO4)2?6H2O was shown to react with 2,2?-[propane-1,3-diylbis(thio-2-phenylnemethylidene]-bis(3-pyridylamine) (I) or (5Z)-2-ethoxycarbonylmethyl-(2-pyridylmethylidene)-3,5-dihydro-4H- imidazol-4-one (II) in the presence of CH3CN with the reduction of copper(II) to copper(I) and the formation of the tetrahedral complex Cu I(CH3CN)4ClO4 (III). In the course of the reaction the organic ligands I and II were oxidized to the corresponding sulfoxides.
