127865-20-7Relevant academic research and scientific papers
Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides
Bukovec, Christian,Kazmaier, Uli
experimental part, p. 2743 - 2750 (2011/05/04)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl]2 as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized buiding blocks in excellent yields.
Benzotriazole-assisted synthesis of novel mannich bases from ketones and diverse aldehydes
Katritzky, Alan R.,Harris, Philip A.
, p. 987 - 996 (2007/10/02)
A wide variety of β-amino ketones are prepared in moderate to good yields by the reaction of the lithium enolates of cyclohexanone, acetophenone, α-tetralone and camphor with the readily available adducts from an aldehyde or ketone, an amine and benzotriazole. Some diastereoselectivity is observed when the benzotriazole adduct is derived from benzaldehyde.
