127876-22-6

Basic information

• Product Name: (1R,2S,4R,5S,6R)-5-phenylthio-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane
• Synonyms: (1R,2S,4R,5S,6R)-5-phenylthio-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane
• CAS NO: 127876-22-6
• Molecular Weight: 236.291
• Mol File: 127876-22-6.mol

Chemical Properties

• CAS DataBase Reference: (1R,2S,4R,5S,6R)-5-phenylthio-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,4R,5S,6R)-5-phenylthio-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane(127876-22-6)
• EPA Substance Registry System: (1R,2S,4R,5S,6R)-5-phenylthio-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane(127876-22-6)

Safety Data

• Hazardous Substances Data: 127876-22-6(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 383193-45-1 (1R,2S,4S,5R,6R)-5-methylsulfonyloxy-3,7,9-trioxatricyclo[4.2.1.0^2,4]nonane 
• 20204-80-2 [(1R,2S,3S,4R,5R)-3-hydroxy-4-(p-tolylsulfonyl)-6,8-dioxabicyclo[3.2.1]oct-2-yl]-4-methylbenzenesulfonic acid 
• 6167-32-4 1,6:3,4-dianhydro-2-O-tosyl-D-galactose 

Downstream Products

• 136632-47-8 1,6-anhydro-2,4-dideoxy-2-(diphenylphosphoryl)-4-phenylthio-β-D-glucopyranose 
• 383193-49-5 (1R,2R,5R)-2,4,4-trimethyl-2-phenylsulfonyl-6,8-dioxabicyclo[3.2.1]octan-3-one 
• 383193-48-4 (1R,2S,3R,5R)-2-phenylsulfonyl-6,8-dioxabicyclo[3.2.1]octan-3-ol 
• 383193-42-8 (1R,2R,5R)-2-phenylsulfonyl-6,8-dioxabicyclo[3.2.1]octan-3-one 
• 383193-46-2 (1R,2S,3R,5R)-2-phenylthio-6,8-dioxabicyclo[3.2.1]octan-3-ol 
• 136632-46-7 1,6-anhydro-2,4-dideoxy-2-(diphenylphosphino)-4-phenylthio-β-D-glucopyranose 

Relevant articles and documents

Synthesis of a C(9)-C(13) fragment of acutiphycin from levoglucosan

Alkylation of (1R,2R,5R)-2-benzenesulfonyl-6,8-dioxa-bicyclo[3.2.1]octan-3-one, which is accessible from levoglucosan, afforded (1R,2R,5R)-2-benzenesylfonyl-2,4,4-trimethyl-6,8-dioxabicyclo[3.2.1]octan-3-one. This was further converted into (1S,2R,3S,5R)-

MEVINIC ACIDS AND ANALOGS : A NOVEL EFFICIENT ROUTE TO CHIRAL SYNTHONS FROM 1,6-ANHYDRO-D-GLUCOSE

1,6-anhydro-D-glucose is efficiently and regioselectively deoxygenated at C-2 and C-4 by displacement of the corresponding ditosylate with thiophenol followed by Raney Ni hydrogenolysis.This route provides a short access to chirons of the key lactonic moi