127880-53-9Relevant academic research and scientific papers
Synthesis of 2-Phenyldecahydroquinolin-4-ones via Imino Diels-Alder Reaction: Influence of the Imine Nitrogen Substituent on the Reaction Course and on the Heterocycle Conformation
Coz, Linda Le,Veyrat-Martin, Christine,Wartski, Lya,Seyden-Penne, Jacqueline,Bois, Claudette,Philoche-Levisalles, Michele
, p. 4870 - 4879 (2007/10/02)
Reaction of acetylcyclohexene trimethylsilyl enol ether (1) with N-substituted phenyl imines 2 takes place in the presence of Lewis acids.When the N-substituent in 2 is phenyl, p-tolyl, or p-methoxyphenyl, the cycloaddition gives exo and endo enoxysilanes
TRIMETHYLSILYL ENOL ETHERS FORMED BY AN IMINO DIELS-ALDER REACTION: MECHANISTIC IMPLICATIONS
Coz, Linda Le,Wartski, Lya,Seyden-Penne, Jacqueline,Charpin, Pierrette,Nierlich, Martine
, p. 2795 - 2796 (2007/10/02)
Diastereomeric silyl enol ethers 3 and 4a-c have been isolated starting from 1 and 2a-c in the presence of AlCl3, implying a concerted process.The structures of 3c and 4c were assigned by single crystal X-ray crystallography.
