127891-07-0Relevant articles and documents
Synthetic studies on neomarinone: practical and efficient stereoselective synthesis of the side chain
Suárez, Rosa M.,Montserrat Martínez,Sarandeses, Luis A.,Pérez Sestelo, José
, p. 6493 - 6495 (2007)
A practical and efficient stereoselective synthesis of the side chain of neomarinone is reported. The synthesis was achieved in six steps (41% overall yield) from 2-methyl-2-cyclohexenone. The key step is a novel stereoselective 1,4-conjugate addition/eno
TOTAL SYNTHESIS OF (+/-)-AGELINE A, A PHYSIOLOGICALLY ACTIVE CONSTITUENT OF AGELAS SPONGES
Asao, Kazuhiko,Iio, Hideo,Tokoroyama, Takashi
, p. 6401 - 6404 (2007/10/02)
The monocyclic diterpene moiety of ageline A (1) was convergently constructed by the palladium-mediated coupling of C9-terpenic chain as vinyl bromide 10 and C11-monocyclic segment as alkylzinc compound 16, which was obtained through a stereoselective cyc