127894-32-0

Basic information

• Product Name: Benzene, 1-chloro-4-(1-hexynylthio)-
• CAS NO: 127894-32-0
• Molecular Formula: C12H13ClS
• Molecular Weight: 224.754
• Mol File: 127894-32-0.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(1-hexynylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(1-hexynylthio)-(127894-32-0)
• EPA Substance Registry System: Benzene, 1-chloro-4-(1-hexynylthio)-(127894-32-0)

Safety Data

• Hazardous Substances Data: 127894-32-0(Hazardous Substances Data)

Upstream product

• 693-02-7 hex-1-yne 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 106-54-7 p-Chlorothiophenol 

Downstream Products

• 1056279-88-9 C₁₈H₁₉ClS 
• 1056279-95-8 C₁₈H₁₈Cl₂S 
• 1056280-01-3 C₁₉H₂₁ClS 
• 1605324-11-5 1-benzyl-4-butyl-5-(4-chlorophenylthio)-1H-1,2,3-triazole 
• 879416-74-7 Tributyl-[(E)-1-(4-chloro-phenylsulfanyl)-hex-1-enyl]-stannane 
• 32922-97-7 S-(4-chlorophenyl) hexanethioate 

Relevant articles and documents

Highly dispersed Ni2P nanoparticles on N,P-codoped carbon for efficient cross-dehydrogenative coupling to access alkynyl thioethers

An ultrafine Ni2P (a metal-rich interstitial phosphide compound) nanoparticles with a narrow size distribution homogeneously dispersed on N,P-codoped carbon was developed for efficient synthesis of alkynyl thioethers via base- and ligand-free cross-dehydrogenative coupling (CDC) of terminal alkynes and thiols using atmospheric air as the oxidant under mild conditions. A remarkable catalytic performance with good functional group compatibility, broad substrate scope and high stability is accomplished. Pyridinic N atoms are identified as basic sites for facilitating the activation of terminal alkynes via hydrogen bonding interactions and play a key role in the success of this base- and ligand-free CDC reaction.

Investigations on Gold-Catalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals

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Iridium-catalyzed intermolecular azide-alkyne cycloaddition of internal thioalkynes under mild conditions

An iridium-catalyzed azide-alkyne cycloaddition reaction (IrAAC) of electron-rich internal alkynes is described. It is the first efficient intermolecular AAC of internal thioalkynes. The reaction exhibits remarkable features, such as high efficiency and r

The hydroboration of 1-alkylthio-1-alkynes, and its application to the syntheses of s-alkyl alkanethioates and (Z)-1-alkylthio-1-alkenes

Hydroboration of 1-alkylthio-1-alkynes with dicyclohexylborane or bis(1,2-dimethylpropyl)borane proceeded smoothly, adding most of the dialkylboryl group to the α-position of the triple bond. The resulting alkenylboranes afforded either S-alkyl alkanethio