127910-22-9Relevant academic research and scientific papers
Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
Rajendran, Kamalraj V.,Gilheany, Declan G.
supporting information; body text, p. 817 - 819 (2012/02/03)
A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
A NEW METHOD FOR THE SYNTHESIS OF OPTICALLY PURE PHOSPHINE OXIDES
Imamoto, Tsuneo,Sato, Kazuhiko,Johnson, Carl R.
, p. 783 - 786 (2007/10/02)
Tertiary phosphine oxides have been prepared with high enantiomeric excesses via intermediate menthyl 2-phosphinylacetates.
