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127910-94-5

(1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene

    Cas No: 127910-94-5

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  • 127910-94-5 Structure

  • Basic information

    1. Product Name: (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene
    2. Synonyms: (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene
    3. CAS NO:127910-94-5
    4. Molecular Formula:
    5. Molecular Weight: 483.475
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 127910-94-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene(127910-94-5)
    11. EPA Substance Registry System: (1R,2S,4R,7R,9S,12S)-12-<(bromomethyl)dimethylsiloxy>-9-methoxy-1-methyl-4-phenyl-3,5,8-trioxatricyclo<8.4.0.02,7>-tetradec-10-ene(127910-94-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 127910-94-5(Hazardous Substances Data)

127910-94-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 127910-94-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,7,9,1 and 0 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 127910-94:
(8*1)+(7*2)+(6*7)+(5*9)+(4*1)+(3*0)+(2*9)+(1*4)=135
135 % 10 = 5
So 127910-94-5 is a valid CAS Registry Number.

127910-94-5Relevant articles and documents

The Stereochemistry of the Stork Silyl Methylene Radical Cyclisation in an Annulated Sugar Derivative

Bonnert, Roger V.,Davies, Michael J.,Howarth, Joshua,Jenkins, Paul R.

, p. 148 - 149 (1990)

Annulated sugar derivatives with α- and β-allylic alcohol groups have been subjected to the Stork silyl methylene radical cyclisation reaction, in both cases, trans-addition of the radical occurred to produce a new fused ring system.

Stereoselective Reductive Hydroxymethylation of an Annulated Sugar Derivative via Radical Cyclisation

Bonnert, Roger V.,Davies, Michael J.,Howarth, Joshua,Jenkins, Paul R.,Lawrence, Nicholas J.

, p. 27 - 30 (2007/10/02)

Addition of a silylmethylene and hydride radical to the carbon-carbon double of two allylic silyl ethers derived from annulated carbohydrates has been shown to occur in an anti fashion.

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