1279102-45-2

Upstream product

• 1279102-44-1 C₁₃H₁₃BrO₂ 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 1279102-61-2 (Z)-((3-bromophenyl)(2-methylenecyclohexylidene)methoxy)trimethylsilane 
• 1279102-72-5 C₂₂H₂₁Br 
• 1279102-85-0 2-(4-(3-bromophenyl)-1,2,5,6,7,8-hexahydronaphthalene-2-yl)furan 
• 1279102-47-4 (3-bromoyphenyl)(2-methylcyclohex-1-en-1-yl)methanone 

Relevant academic research and scientific papers

Enabling the development of N-Heterocyclic Carbene (NHC) catalyzed reactions: Practical methods for the preparation of 1-acyl-2-alkylcycloalkenes from cycloalkanones

The synthesis of 1-acyl-2-alkylcycloalkenes from a variety of cycloalkanones has been achieved via either-keto enol phosphates or-bromoenones. Both methods exploit simple and readily scalable transformations allowing the preparation of the desired compoun

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.