1279102-75-8

Upstream product

• 1279102-57-6 (2-methyl-3,4-dihydronaphthalen-1-yl)(phenyl)methanone 
• 1279102-55-4 (2-bromo-3,4-dihydronaphthalen-1-yl)(phenyl)methanol 
• 1279102-56-5 (2-bromo-3,4-dihydronaphthalen-1-yl)(phenyl)methanone 
• 1279102-65-6 (E)-trimethyl((2-methylene-3,4-dihydronaphthalen-1(2H)-ylidene)(phenyl)methoxy)silane 
• 38986-89-9 trans-cinnamoyl fluoride 
• 112631-07-9 2-bromo-3,4-dihydro-1-naphthaldehyde 

Relevant academic research and scientific papers

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.