127929-63-9Relevant academic research and scientific papers
A New Synthetic Route to Optically Active α,β- and β',γ'-Unsaturated Alkohols, and Its Application to the Synthesis of a Fungitoxic C-18 Hydroxy Unsaturated Fatty Acid
Kashihara, Hiroshi,Suemune, Hiroshi,Fujimoto, Katsuhiko,Sakai, Kiyoshi
, p. 2610 - 2614 (2007/10/02)
A new synthetic route to optically active α,β-, β',γ'-unsaturated alcohols was established.The chiral enones (6 and 8), prepared from dimethyl malate via chiral phosphonates (4 and 5), were diastereoselectively reduced with Zn(BH4)2 to afford the 1,3-syn
