127956-56-3Relevant academic research and scientific papers
1,5-Dipolar electrocyclizations of thiocarbonyl ylides bearing C=N groups: Reactions of N-[(dimethylamino)methylene]thiobenzamide and 2-(dimethylhydrazono) -1-phenylethane-1-thione with diazo compounds
Egli, Daniel H.,Linden, Anthony,Heimgartner, Heinz
, p. 86 - 100 (2007)
The reactions of thiobenzamide 8 with diazo compounds proceeded via reactive thiocarbonyl ylides as intermediates, which underwent either a 1,5-dipolar electrocyclization to give the corresponding five membered heterocycles, i.e., 4-amino-4,5-dihydro-1,3-
Addition of trimethylsulfoxoniumylide and methylenetriphenylphosphorane to N2-thioacylamidines
Toure, S. A.,Voglozin, A.,Degny, E.,Danion-Bougot, R.,Danion, D.,et al.
, p. 574 - 579 (2007/10/02)
Trimethylsulfoxonium ylide reacts with 4-dimethylamino-1-thia-3-azabutadienes (N2-thioacylamidines) affording thiazol-2-ines, through a regioselective reaction corresponding to a nucleophilic attack on the amidine group.Thiazoles are obtained b
