1279718-35-2Relevant academic research and scientific papers
Rh2(II)-catalyzed nitro-group migration reactions: Selective synthesis of 3-nitroindoles from β-nitro styryl azides
Stokes, Benjamin J.,Liu, Sheng,Driver, Tom G.
, p. 4702 - 4705 (2011/05/16)
Rhodium carboxylate complexes (1 mol %) catalyze the migration of electron-withdrawing groups to selectively produce 3-substituted indoles from β-substituted styryl azides. The relative order of migratorial aptitude for this transformation is ester ? amide H sulfonyl benzoyl ? nitro.
