128025-85-4

Upstream product

• 18399-61-6 Mo(CO)5(PPh2H) 
• 153147-87-6 ((phenyl)2HCCH₂P)pentacarbonylmolybdenum 
• 190001-00-4 (CO)5Mo((C₆H₅)2PCH₂CCH₂P(C₆H₅)2)Mo(CO)5 
• 127931-22-0 2,3-bis-(diphenylphosphino)propene 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 128025-91-2 cis-tetracarbonyl(1,2,3-tris(diphenylphosphino)propane-PP')Mo⁽⁰⁾ 
• 128025-88-7 cis-(cis-1,2-bis(diphenylphosphino)propenePP')(tetracarbonyl)Mo⁽⁰⁾ 

Relevant academic research and scientific papers

Molybdenum carbonyl complexes of di- and triphosphines: Hydrophosphination reactions of (HC≡CCH2PPh2) Mo(CO)5

The base catalyzed hydrophosphination reactions of (HC≡CCH2PPh2)Mo(CO)5 with Ph2PH and (Ph2PH)Mo(CO)5 give several different products as a function of reaction conditions. These products we

Addition Reactions and Rearrangements of 2,3-Bis(diphenylphosphino)propene and its Complexes with Group 6 Metal Carbonyls: Routes to Complexes of 1,2,3-Tris(diphenylphosphino)propane

The preparation of 2,3-bis(diphenylphosphino)propene (1) and its Group 6 metal tetracarbonyl complexes are described.The attempted base-catalysed addition of PR2H to (1) results in rearrangement to trans-1,2-bis(diphenylphosphino)propene (2) instead of the expected triphenylphosphine.Under the same conditions the Group 6 metal carbonyl complexes of (1) can rearrange to complexes of the cis isomer of (2), but may also undergo the addition reaction to yield M(CO)4 complexes of the new ligand 1,2,3-tris(diphenylphosphino)propane by adjustment of the reaction conditions.These on heating yield the corresponding M(CO)3 complexes.Proton, 13C, and 31P n.m.r. spectral parameters of the new compounds are presented and are discussed in terms of metal- and backbone-mediated contributions and co-ordination chemical shifts.