128032-29-1Relevant academic research and scientific papers
ALKALINE METAL FLUORIDES IN GRAPHITE - NEW CATALYSTS IN ORGANIC SYNTHESIS. I. REACTIONS OF POLYFLUOROAROMATIC COMPOUNDS WITH O- AND N-NUCLEOPHILIC AGENTS
Aksenov, V. V.,Vlasov, V. M.,Danilkin, V. I.,Rodionov, P. P.,Shnitko, G. N.
, p. 57 - 73 (1990)
The paper reports the use of new catalysts - alkaline metal fluorides in graphite of the general formula C8MF, where M=Li, Na, K, Rb or Cs, in the reactions of polyfluoroaromatic compounds with aromatic OH-acids and piperidine.These compounds are shown to have a high activity in the above processes, exceeding that of similar free fluorides of alkaline metals.
Unusual lability of pentafluorophenoxy group in reactions of potassium aroxides with pentafluoropyridine
Vlasov,Aksenov,Rodionov,Beregovaya,Shchegoleva
, p. 115 - 125 (2007/10/03)
The kinetics of the reactions of pentafluoropyridine with potassium aroxides, leading to formation of polyfluorinated aryl pyridyl ethers, conform to the Bronsted equation. The data obtained for potassium pentafluorophenoxide deviate from the general corr
