128050-46-4Relevant academic research and scientific papers
STEREOSELECTIVE PREPARATION OF SYNTHETIC EQUIVALENTS OF 2-DEOXY-2-AMINO- AND 3-DEOXY-3-AMINOTETROSES FROM MALIC ACID. APPLICATION TO THE SYNTHESIS OF C18-D-RIBO-PHYTOSPHINGOSINE
Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica
, p. 5507 - 5510 (1989)
"Electrophilic amination" of β-hydroxyester 5, derived from (S)malic acid, with di-t-butylazodicarboxylate allowed preparation of new synthetic equivalents of 2-deoxy-2-amino- and 3-deoxy-3-amino-tetroses.As an application, D-ribo-C18-phytosphingosine was stereoselectively synthesized.
