1280729-10-3Relevant academic research and scientific papers
Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPOSS) with enhanced solubility
Moore, Brian M.,Ramirez, Sean M.,Yandek, Gregory R.,Haddad, Timothy S.,Mabry, Joseph M.
, p. 2676 - 2680 (2011)
Four new asymmetric Polyhedral Oligomeric SilSesquioxanes (POSS) with the formula (Aryl)Phenyl7Si8O12, where Aryl = 1-naphthyl, 2-naphthyl, 9-phenanthrenyl, and 1-pyrenyl, have been synthesized in reasonable yield and high purity. These compounds were characterized with 1H, 13C, 29Si NMR and elemental combustion analysis. These compounds possess polycyclic aromatic functionality, which disrupts symmetry to improve solubility in organic solvents and aromatic polymers, without significant impact on thermal stability.
Synthesis and applications of peripherally asymmetric aryl POSS compounds
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Page/Page column 6, (2015/04/28)
Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPoss) compounds synthesized by the “corner-capping” of phenyl7Si7O9(OH)3 with aryl trichlorosilanes are described. The ArPoss compounds have the chemical
