128103-48-0Relevant academic research and scientific papers
Aryl Nitrile Oxide Cycloaddition Reactions in the Presence of Baker's Yeast and β-Cyclodextrin
Easton, Christopher J.,Hughes, C. Merricc M.,Tiekink, Edward R. T.,Savage, G. Paul,Simpson, Gregory W.
, p. 629 - 632 (2007/10/02)
Contrary to recent reports, baker's yeast is not required for reactions of nitrile oxides with either ethyl cinnamate or 4-vinylpyridine to give isoxazolines. β-Cyclodextrin may alter the ratio of isomers isolated from the reactions of the cinnamate but only at concentrations of reactants much lower than those reported, and this effect is most likely due to selective product complexation rather than selective product formation.
A regioselective enzyme catalyzed cycloaddition
Rama Rao,Bhanumathi,Srinivasan,Sattur
, p. 899 - 902 (2007/10/02)
Baker's Yeast catalyzed the regioselective cycloaddition of nitrileoxides 1 to cinnamic esters 2. Reversal of regioselectivity is observed in these cycloadditions by using β-cyclodextrin as an artificial enzyme along with baker's Yeast.
