128175-77-9

Basic information

• Product Name: (-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate
• Synonyms: (-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate
• CAS NO: 128175-77-9
• Molecular Weight: 282.267
• Mol File: 128175-77-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate(128175-77-9)
• EPA Substance Registry System: (-)-S-t-butyl(phenyl)-S-trifluoromethyl phosphinothioate(128175-77-9)

Safety Data

• Hazardous Substances Data: 128175-77-9(Hazardous Substances Data)

Upstream product

• 55705-77-6 (S)-(-)-tert-butyl(phenyl)phosphinothioic acid 
• 372-64-5 Bis(trifluoromethyl)disulfid 
• 82945-11-7 (R_p)-t-butyl(phenyl)phosphine oxide 

Downstream Products

• 55236-56-1 tert-Butyl(phenyl)phosphinsaeurefluorid 

Relevant articles and documents

TRANSFORMATION OF ORGANOPHOSPHORUS S-TRIFLUOROMETHYLTHIOATES RR'P(O)SCF3 INTO FLUORIDES RR'P(O)F. STEREOCHEMICAL ASPECTS OF THIOCARBONYL FLUORIDE EXTRUSION

The stereochemical course of the thermal or by nucleophiles catalyzed extrusion reaction of thiocarbonyl fluoride from two diastereomeric (6) and optically active (10) organophosphorus S-trifluoromethylthioates has been investigated.To explain the observed retention of configuration at phosphorus in fluoridates 7 formed in the thermal reactions, a four center transition state for such reactions has been proposed.The lack of the stereoselectivity in the catalyzed reactions of 6, and the observed racemization of the final product 11 are briefly discussed.