1281983-36-5Relevant academic research and scientific papers
Metal-mediated synthesis of antiaromatic porphyrinoids from a BODIPY precursor
Sakida, Takafumi,Yamaguchi, Shigeru,Shinokubo, Hiroshi
, p. 2280 - 2283 (2011/04/21)
(Figure Presented) Metallic route to antiaromaticity: The synthesis of a butadiyne-bridged cyclic BODIPY dimer (see structure; C white, B orange, N blue, F green) and trimer was achieved through Pd-catalyzed Stille coupling and Cu-mediated Glaser-type coupling. These cyclic BODIPYs were found to be stable 24π- and 36π-antiaromatic porphyrinoids with planar conformations, and their structures, electronic states, and reactivity were explored.
