128266-02-4Relevant academic research and scientific papers
Cationic cyclization of regular α-monoterpenols as a model for tri- And tetracyclic diterpene biosynthesis
Veselovsky,Dragan,Moiseenkov
, p. 1187 - 1190 (1990)
Low-temperature boron trifluoride etherate initiated cyclization of α-geraniol, α-nerol, and α-linalool leads to regioisomeric dimethylvinylcyclohexenes possessing a rare monoterpene carbon skeleton along with bicyclo[3.2.1]octyl fluoride. The cyclization mimics biosynthesis of tri- and tetracyclic diterpenes according to Wenkert.
ELECTROPHILIC CYCLIZATION OF α-MONOTERPENOLS AS A MODEL FOR THE BIOSYNTHESIS OF TRI- AND TETRACYCLIC DITERPENES
Moiseenkov, A. M.,Veselovskii, V. V.,Dragan, V. A.,Ignatenko, A. V.,Strelenko, Yu. A.
, p. 1233 - 1237 (2007/10/02)
Low temperature electrophilic cyclization of α-geraniol, α-nerol, and α-linalool initiated by BF3*etherate leads to the formation of dimethylvinylcyclohexenes and bicyclooctyl fluoride, which have monoterpene skeletons.The α-monoterpenol starting materials may be regarded as close models to labdadienols, and their transformation as mimicking the biosynthesis of diterpenes in the pimarane and gibbane series according to Wenkert.
