128307-47-1Relevant academic research and scientific papers
Highly Chemoselective and Stereoselective Conjugate Addition of Benzyl Copper Reagents to α-Oxoketene Dithioacetals
Mehta, Barun K.,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 1925 - 1928 (2007/10/02)
Benzyl copper reagents derived by transmetallation between benzylmagnesium chloride and Cu(I) species are shown to undergo conjugate addition - elimination with acyclic and cyclic α-oxoketene dithioacetals to afford the corresponding β-benzyl vinylogous t
Regio- and chemoselective conjugate 1,4-reduction of α-oxoketene dithioacetals with sodium borohydride and sodium cyanoborohydride
Srinivasa Rao,Chakrasali,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 2195 - 2204 (2007/10/02)
Theα-oxoketene dithioacetals 1 are shown to undergo conjugate 1,4-reduction in highly regio- and chemoselective manner with sodium borohydride in acetic acid to afford the corresponding β-oxodithioacetals 5 in good yields. These results have been rational
