128316-29-0Relevant academic research and scientific papers
The effect of thallium(I) salts on palladium catalysed tandem cyclisation-anion capture processes
Grigg,Loginathan,Sukirthalingam,Sridharan
, p. 6573 - 6576 (2007/10/02)
The effect of the addition of 1 mol. of various additives [NEt4Cl, Ag(I) and Tl(I) salts] on selectively suppressing direct capture processes has been studied for hydride ion transfer (from formate) and phenyl transfer (from PhZnCl). The additives can promote cyclisation-anion capture at the expense of direct capture with Tl(I) salts being especially useful although in one case NEt4Cl promotes direct capture. The addition of Tl(I) formate diverts the cyclisation-hydride ion capture process into a new reaction channel in one case.
