1283231-72-0Relevant academic research and scientific papers
Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes
Magre, Marc,Maity, Bholanath,Falconnet, Alban,Cavallo, Luigi,Rueping, Magnus
supporting information, p. 7025 - 7029 (2019/04/26)
A magnesium-catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium c
Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes
Kim, Hye Ryung,Yun, Jaesook
supporting information; experimental part, p. 2943 - 2945 (2011/05/04)
The copper-catalyzed addition of bis(pinacolato)diboron to internal alkynes in the presence of methanol generates alkenylboron compounds with high levels of regio- and stereoselectivities. The catalytic efficiency is increased by using monodentate phosphine ligands, especially P(p-tolyl)3 and a range of internal alkynes was borylated in good yields. The Royal Society of Chemistry.
