128326-88-5

Basic information

• Product Name: {(cyclopentadienyl)tris(dimethylphosphito-P)cobalt-O,O',O''}(trans-4-phenyl-3-butene-2-one)copper(I)
• CAS NO: 128326-88-5
• Molecular Weight: 564.951
• Mol File: 128326-88-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(cyclopentadienyl)tris(dimethylphosphito-P)cobalt-O,O',O''}(trans-4-phenyl-3-butene-2-one)copper(I)(CAS DataBase Reference)
• NIST Chemistry Reference: {(cyclopentadienyl)tris(dimethylphosphito-P)cobalt-O,O',O''}(trans-4-phenyl-3-butene-2-one)copper(I)(128326-88-5)
• EPA Substance Registry System: {(cyclopentadienyl)tris(dimethylphosphito-P)cobalt-O,O',O''}(trans-4-phenyl-3-butene-2-one)copper(I)(128326-88-5)

Safety Data

• Hazardous Substances Data: 128326-88-5(Hazardous Substances Data)

Upstream product

• 64443-05-6 tetrakis(actonitrile)copper(I) hexafluorophosphate 
• 122-57-6 1-Phenylbut-1-en-3-one 

Relevant articles and documents

Alkene, Alkyne, Isonitrile, and Carbonyl Complexes of Copper(I) and Silver(I) with Tris-Chelating Oxygen Ligands

The preparation of η2-alkynecopper(I) complexes of the composition RCu(η2-alkyne)>, alkyne = tolan, dimethyl acetylenedicarboxylate, is described.LR- are anionic tris-chelating oxygen ligands of the type 3>-, R = OMe, OEt, O-i-Pr.The isonitrile complexes RM(CN-t-Bu)>, M = Cu, Ag, have been prepared from OMeCu(CO)> and OEt>2>, respectively.The silver carbonyl complex OEtAg(CO)> -1> forms in hexane and methanol solutions of OEt>2> under 1 atm of CO gas.The olefin complexes RCu(ba)>, ba = benzylidene acetone, have been prepared from PF6, NaLOMe, and ba and from the carbonyl complex OEtCu(CO)> and ba.The coordination of the carbon-carbon double bond of ba at the LRCu fragment does not lead to a 1,4-addition of methyllithium to the α,β-unsaturated ketone.