128328-90-5Relevant academic research and scientific papers
Synthesis, structure, and photochemical reaction of 9,10-dihydro-9-silaanthracene derivatives carrying bulky substituents
Nishiyama, Kozaburo,Oba, Makoto,Takagi, Hidenori,Fujii, Isao,Hirayama, Noriaki,Narisu,Horiuchi, Hiroaki,Okutsu, Tetsuo,Hiratsuka, Hiroshi
, p. 20 - 26 (2000)
Some of 9-aryl-9,10-dihydro-9-silaanthracenes (1) were prepared and the alkylation of the compounds gave trans-9-aryl-10-alkyl-9,10-dihydro-9-silaanthracenes exclusively. Upon photolysis of a 9-phenyl derivative, 9-phenyl-9-silaanthracene was confirmed by
Photochemical Formation of 9-Silaanthracenes in Rigid Glass
Hiratsuka, Hiroshi,Tanaka, Mieko,Okutsu, Tetsuo,Oba, Makoto,Nishiyama, Kozaburo
, p. 215 - 216 (1995)
UV photolysis of 9,10-dihydro-9-silaanthracenes in 3-methylpentane glass at 77 K results in the formation of 9-silaanthracenes and diphenylmethyl-type radicals; by use of a triplet quencher, it was confirmed that these were produced via the lowest triplet state.
Neutralization-Reionization Mass Spectrometry and Matrix Isolationof Some 9-Silaanthracenes
Winkel, Yvar van den,Baar, Ben L. M. van,Bickelhaupt, Friedrich,Kulik, Willem,Sierakowski, Claudia,Maier, Guenther
, p. 185 - 190 (2007/10/02)
Neutralization-reionization mass spectrometry of silanthracene radical cations, which are generated from the 9,10-diydro-9-silaanthracenes 1, 3, 8 and 11 under electron-impact conditions, indicates that silaanthracenes are stable molecules in the gas phase.Flash pyrrolysis of the starting compounds mentioned above also yields also silaanthrecenes 2, 4, and 10, which may be isolated in an argon matrix at 15 K and exhibit characeristic UV-spectra.
