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128337-02-0

2-(phenylthio)tricyclo<3.3.1.13,7>decane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 128337-02-0 Structure

  • Basic information

    1. Product Name: 2-(phenylthio)tricyclo<3.3.1.13,7>decane
    2. Synonyms: 2-(phenylthio)tricyclo<3.3.1.13,7>decane
    3. CAS NO:128337-02-0
    4. Molecular Formula:
    5. Molecular Weight: 244.401
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 128337-02-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-(phenylthio)tricyclo<3.3.1.13,7>decane(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-(phenylthio)tricyclo<3.3.1.13,7>decane(128337-02-0)
    11. EPA Substance Registry System: 2-(phenylthio)tricyclo<3.3.1.13,7>decane(128337-02-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 128337-02-0(Hazardous Substances Data)

128337-02-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 128337-02-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,8,3,3 and 7 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 128337-02:
(8*1)+(7*2)+(6*8)+(5*3)+(4*3)+(3*7)+(2*0)+(1*2)=120
120 % 10 = 0
So 128337-02-0 is a valid CAS Registry Number.

128337-02-0Relevant articles and documents

Photochemistry of phenyl thioethers and phenyl selenoethers. Radical vs ionic behavior

Kropp, Paul J.,Fryxell, Glen E.,Tubergen, Mark W.,Hager, Michael W.,Harris Jr., G. Davis,McDermott Jr., T. Paul,Tornero-Velez, Rogelio

, p. 7300 - 7310 (2007/10/02)

In analogy with alkyl iodides and bromides, the phenyt thio- and selenoethers 2a,b, 13a, 21b,c and 35 displayed competing radical and ionic photobehavior on irradiation in solution, via a mechanism thought to involve initial homolytic cleavage of the alkyl C-S or C-Se bond followed by electron transfer within the resulting radical pair cage (Scheme I). These are the first examples of ionic photobehavior to be recognized for the C-SAr and C-SeAr chromophores. The electronegatively substituted pentafiuorophenyl analogues 2c, 13b, and 21d displayed enhanced ionic photobehavior. By contrast, the 4-methoxyphenyl derivative 21a exhibited almost exclusively radical behavior. The sulfoxide (2R*,R*s)-21f displayed principally radical behavior, accompanied by epimerization at sulfur. The quantum yields for the disappearance of the 2-norbornyl ethers 21b and 21c were 0.53-0.64 in solution and rose to 0.89-0.95 in the presence of suspended fumed silica. Irradiation of the phenyl thioether 21b on silica gel resulted in nucleophilic trapping by surface silanol groups to afford covalently bound material (33), which afforded chloride 34 on treatment with SOCl2. Irradiation of phenyl thioethers 2a and 35, phenyl selenoether 2b, or C6H5SH in allyl alcohol solution afforded acetal 11, apparently via isomerization of some of the solvent to propanal (44) followed by acetalization. Irradiation of alcoholic solutions of aldehydes containing C6H5SH is a useful means of generating acetals under neutral conditions.

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